Synthesis, characterization and chelating properties of tannin-8-hydroxy quinoline - formaldehyde polymer

T Sasikala; KP Greeshma; Priya K Gnana; S Muthulingam; C Nandhakumar

doi:10.30574/gscarr.2020.5.2.0083

Authors

T Sasikala Department of Chemistry, Sri Ramakrishna College of Arts and Science (SRCAS), Coimbatore – 641006.
KP Greeshma Department of Chemistry, Sri Ramakrishna College of Arts and Science (SRCAS), Coimbatore – 641006.
Priya K Gnana Department of Chemistry, Sri Ramakrishna College of Arts and Science (SRCAS), Coimbatore – 641006.
S Muthulingam Department of Chemistry, Sri Ramakrishna College of Arts and Science (SRCAS), Coimbatore – 641006.
C Nandhakumar Department of Chemistry, Sri Ramakrishna College of Arts and Science (SRCAS), Coimbatore – 641006.

DOI:

https://doi.org/10.30574/gscarr.2020.5.2.0083

Keywords:

Tannin, 8-hydroxy Quinoline, Metal Chelates, Spectral Study, Thermogravimetry, Magnetic Moments

Abstract

Tannin obtained from Eucalyptus plant, condensed with formaldehyde and then 8-hydroxy quinoline. The so called obtained polymer designated as TFQ was used for metal chelate formation. Thus Transition metal chelates of TFQ with Zn⁺², Co⁺², Cu⁺², Ni⁺² and Mn⁺² metal ions were prepared. The ligand TFQ and its all five metal chelates were characterized by nitrogen content, IR, UV-Visible spectral studies, magnetic moments and thermogravimetry. The antimicrobial activity of all the samples has also been monitored against common microbes.

Metrics

Metrics Loading ...

References

Ciesilski T., Pastukhov M.V., Szefer P., Jensen B.M., Bioaccumulation of Mercury in the pelagic food chain of lake Baikal, Chemosphere.1984;78: 1378-1389.

Loukidou,M.X., A.I.Zouboulis, T.D. Karapantsios and K.A. Matis, Physiochemical and Engineering Aspect. 2004 ;242(89): 93- 104.

B.A. Shah, A.V. Shah, B.N. Bhandaria, R.R. Bhatt,Synthesis, Characterization and Chelation Ion-Exchange Studies of a Resin Copolymer Derived from 8-Hydroxy quinoline -Formaldehyde-Catechol. J. Iran. Chem. Soc. 2008; 5(2): 252-261.

D.T. Masram, K.P. Kariya, N.S. Bhave, : Electrical conductivity study of resin synthesized from salicylic acid, butylenediamine and formaldehyde. Arch. Apll. Sci. Res. 2010; 2 (2): 153-161.

Gurnule W.B and Thakre M. B. Synthesis and Characterization of High Performance Terpolymer Resin Derived from 8- Hydroxyquinoline and Adipamide, Scholars Research Library, Der Pharma Chemica. 2011; 3 (6): 235-242.

Raj. J.A., Vedhi. C., Burkanudeen A., Arumugam P. and Manishankar P. Synthesis and characterization of novel nano-size, Poly Reactive. 2010; 16: 171-175,

Shah B.A., Shah A.V. and Bhatt R.R. Studies of chelation ion-exchange properties of copolymer resin derived from salicylic acid and its analytical applications, Iranian Polym. J. 2007; 16(3): 173-184.

JC Patel, HR Dholariya, KS Patel, KD Patel, Appl. Organomett, Chem. 2012; 26(24): 604-610.

Gurnule W.B. and Bisen V. R., Kinetics of Thermal Decomposition of Copolymer Resin-II Derived from 4- hydroxylbenzaldehyde, Phenyl hydrazine and Formaldehyde. Research Journal of Pharmaceutical, Biological and Chemical Sciences. 2014; 5(4): 1283-1298,. .

Pan J., Plant J. A., Voulvouliis N. Oater C. J., Ihlenfeld C., Cadmium Levels, In Europe: Implication for human health, Environ. Geochem. Health .2010; 32: 1 – 12.

Vilayatkar N.D., Gadegone S.M. and Rahangdale P.K., Removal of Carcinogenic Cr(Vi) Using Cajanus Cajan Pericarp Activated Carbon , International Journal of Recent Scientific Research Research. 2014; 5(9): 1654-1657.

CD Doyel, "Quantitative calculations in thermogravimetric analysis" Marcel Dekker, Inc., New York. 1966; 32: 287-312.

WR. Baily, EG Scott, C V Moshy Co.St.Lovis, Diagnostic Microbiology.1966; 12(7): 257.

Kumar, A. Praveen; Reddy, P. Raveendra and Reddy, V. Krishna Indian Journal of Chemistry., 2007, 46, 1625-1629.