Extraction, production and characterization of biodiesel from shea butter (Vitellaria paradoxa C. F. Gaertn) obtained from Hadejia, Jigawa State, Nigeria
DOI:
https://doi.org/10.30574/gscbps.2020.11.3.0168Keywords:
Biodiesel, Shea butter, Shea butter oil, TransesterificationAbstract
Biodiesel, a form of diesel fuel, is an alternative fuel similar to the conventional diesel (the fossil) and can be produced from vegetable oils, animal oils and fats, tallow and waste cooking oils. In this study, oil was extracted from shea butter, and then subjected to transesterification process to convert it to biodiesel. Both the oil and the biodiesel were characterized using the standard procedures. The results showed that the oil has a density of 923.82 Kgm3, refractive index of 1.464, viscosity of 4.5 mm2/s at 40OC, acid value of 1.84 mgKOH/g, saponification value of 189.53 mgKOH/g, flash point of 338OC and iodine value of 35.52 mgI2/g. While the results for the biodiesel showed that it has a density of 887.61 Kgm3, refractive index of 1.441, viscosity of 3.62 mm2/s at 40OC, acid value of 0.37 mgKOH/g, saponification value of 265.81 mgKOH/g, flash point of 96OC and iodine value of 34.24 mgI2/g. These results were found to be within the ranges of American Society for Testing and Materials (ASTM) specification.
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Alajtal AI, Sherami FE and Elbagermi MA. (2018). Acid, Peroxide, Ester and Saponification Values for Some Vegetable Oils Before and After Frying AASCIT Journal of Materials, 4(2), 43-47.
Amo-Tanta, BMW and Onigbinde AO. (2013). Physicochemical Properties and Fatty Acid Profile of Crude Oil Extracts from Three Vegetable Seed Pakistan Journal of Nutrition, 12(7), 647-650.
AOAC International. (2000). Official Methods of Analysis of AOAC Internatinal. 17th Edn. Gaithersburg, MD: AOAC International.
Arjun BC, Martin ST, Suzanne MB, Chris KW and Rafiqul-Islam. (2008). Non-Edible Plant Oils as New Sources for Bidiesel Production, International Journal of Molecular Science, 9(2), 169-180.
Atabani AE, Silitonga AS, Ong HC, Mahlia TMI, Masjuki HH, Badruddin IA and Fayaz H. (2013). Non-Edible Vegetable Oils: A Critical Evaluation of Oil Extraction, Fatty Acid Composition, Biodiesel Production, Characteristics, Engine Performance and Emissions Production, Renewable and Sustainable Energy Reviews, 18, 211-245.
Ayhan D, Abdullah B, Waqar A and Manzoor S. (2016). Biodiesel Production from Non-Edible Plant Oils, Energy Exploration and Exploitation, 34(2), 290-318.
Blomqvist P, Evegren F, Willstrand O and Arvidson M. (2015). Preflash - Preliminary Study of Protection Against Fire in Low-Flash Point Fuel. Science Partner Report. SP Technical Research Institute of Sweden, 1-5.
Canakci M and Van Gerpen J. (1999). Biodiesel Production Via Acid Catalysis, Transactions of the ASAE, 42(5), 1203-1210.
Chibor BS, Kiin-Kabari DB and Eke-Ejiofor J. (2017). Physicochemical Properties and Fatty Acid Profile of Shea Butter and Fluted Pumpkin Seed Oil: A Suitable Blend in Bakery Fat Production, International Journal of Nutrition and Food Sciences, 6(3), 122-128.
Egan H, Kirk RS and Sawyer R. (1985). Pearson’s Chemical Analysis of Foods. Churchill Livingstone, London, 520-550.
Enweremadu CC and Alamu OJ. (2011). Development and Characterization of Biodiesel from Nigerian Shea Nut Butter (Vitellaria paradoxa), International Agrophysics, 24, 29-34.
Enweremadu CC, Rutto HL and Peleowo N. (2011). Performance Evaluation of a Diesel Engine Fueled with Methy Ester of Shea Butter,World Academy of Science Engineering and Technology, 79, 135-139.
Ghadge SV And Raheman H. (2005). Biodiesel Production from Mahua (Madhuca indica) Oil having High Free Fatty Acids, Biomass Bioenergy, 28(6), 601-605.
Gimbun J, Ali S and Kanwal CC. (2013). Biodiesel Production from Rubber Seed Oil using a Limestone Based Catalyst, Advances in Materials Physics and Chemistry, 2(4), 138-143.
Goh E. (1994). Formulation of Lauric Oil Containing Food Products and their Performances. In: Proceedings of World Conference on Lauric Oils: Sources, Processing and Applications, Applewhite, T. H(ed). The American Oil Chemists Society, USA, 38-103.
Hamilton RJ and Rossell JB. (1986). Analysis of Oils and Fats. Elsevier Applied Science. New York, Chi, 53.
Heroor SH and Bharadwaj SDR. (2013). Production of Bio-Fuel from Crude Neem Oil and its Performance. International Journal of Environmental Engineering and Management, 4, 425-432.
Ho DP, Ngo HH and Guo W. (2014). A Mini Review on Renewable Sources for Biofuel. Bioresource Technology, 169, 742-749.
Ikaya JK, Umengar LN and Lobee A. (2013). Effect of Extraction Methods on the Yield and Quality Characteristics of Oils from Nut, Journal of Food Research Science, 2, 1-12.
Ike E, Yerima JB and Dikko AB. (2018). Determination of the Viscosity and Density of Mahogany Seed Oil IOSR Journal of Engineering, 08(2), 08-13.
Jude E and Benjamin A. (2014). Production of Biodiesel from Shea Butter Oil using Homogeneous Catalysts, Leonardo Journal of Sciences, 12, 39-48.
Kanna AR, Purushotham ST, Sreerag KS, Sooraj PS, Vipin Raj RA and Arun KS. (2017). Experimental Analysis of Flash Point of Lubricating oil. International Refereed Journal of Engineering and Science, 6(4), 53-55.
Kotoka F, Tulashie SK and Setsoafia DD. (2017). Production of Bioethanol from Liquid Waste from Cassava Dough during Garri Processing, Biofuels, 10(4), 493-501.
Maitera ON, Louis H, Dass PM, Akakuru UO and Joshua Y. (2017). Production and Characterization of Biodiesel from Coconut Extraxt (Cocos nucifera), World News of Natural Sciences, 9, 62-70.
Mulugetta Y. (2009). Evaluating the Economics of Biodiesel in Africa, Renewable and Sustainable Energy reviews, Elsevier, 13(6-7), 1592-1598.
Nourrechni H, Teoh BC and Clement ID. (1992). Viscosity of Vegetable Oils and Fatty Acids, Journal of American Chemical Society, 69, 1184-1188.
Obibuzur JU, Abigor RD, Omamor I, Omoriyekemen V, Okogbenin EA and Okunwaye T. (2014). A Two-Year Seasonal Survey of the Quality of Shea Butter Produced in Niger State of Nigeria, African Journal of Food Scieces, 8(2), 64-74.
Odisu T, Akemu A, Obahiagbon KO and Anih EC. (2019). Comparative Studies on the Production of Biodiesel from Shea Nut Oil by Acid Catalyzed and Supercritical Transesterification Processes, Journal of Applied Sciences and Environmental Management, 23(2), 349-357.
Okullo JBL, Omujal F, Agea JG, Vuzi PC, Namutebi A, Okello JBA and Nyanzi SA. (2010). Physico-Chemical Characteristics of Shea Butter (Vitellaria Paradoxa C.F. Gaertn.) Oil from the Shea Districts of Uganda, African Journal of Food Agriculture Nutrition and Development, 10(1), 2070-2084.
Olaniyan AM and Oje K. (2007). Quality Characteristics of Shea Butter Recovered from Shea Kernel through Dry Extraction Process, Journal of Food Science Technology, 44, 404-407.
Ong HC, Mahli TMI and Masjuki HH. (2011). Comparison of Palm Oil, Jatropha curcas and Calophyllum inophyllum for Biodiesel: A Review. Renewable and Sustainable Energy Reviews, 15(8), 3501-3515.
Padhi SK and Singh RK. (2010). Optimization of Esterification and Transesterification of Mahua (Madhuca indica) Oil for Production of Biodiesel, Journal of Chemical and Pharmaceutical Research, 2(5), 599-608.
Ramadhs AS, Jayaral S and Muraleedharan C. (2004). Use of Vegetable Oils as IC Engine Fuels: A Review, Renewable Energy, 29(5), 727-742.
Samuel KT, Pranjal K, Francis K, Oscar KS and Livingstone Q. (2018). Biodiesel Production from Shea Butter: A Suitable Alternative Fuel to Premix Fuel, Materialia, 3, 288-294.
Sarin R, Sharma M, Sinharay S and Malhotra RK. (2007). Jatropha-Palm Biodiesel Blends: An Optimum Mix for Asia, 86, 1365-1371.
Schumann K and Siekmann K. (2005). Soaps. Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH, 247.
Shahidi F. (2005). Quality Assurance of Fats and Oils: In: Bailey’s Industrial Oil and Fats Products, Shahidi F. (Ed). 6A Edn. John Wily and Sons Inc. USA, 47.
Shay EG. (1993). Diesel Fuel from Vegetable Oils: Status and Opportunities, Biomass Bioenergy, 4, 227-242.
Thangaraj B, Ramachandran KB and Raj SB. (2014). Homogeneous Catalytic Transesterification of Renewable Azadirachta indica (Neem) Oil and its Derivatives to Biodiesel Fuel Via Acid/Alkaline Esterification Processes, International Journal of renewable Energy and Biofuels, 11, 1-16.
Tulashie SK and Salifu S. (2017). Potential Production of Biodiesel from Green Microalgae, Biofuels, 11(2), 201-208.
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